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Abstract Decameter hectometric (DH; 1–14 MHz) type IV radio bursts are produced by flare-accelerated electrons trapped in postflare loops or the moving magnetic structures associated with the coronal mass ejections (CMEs). From a space weather perspective, it is important to systematically compile these bursts, explore their spectrotemporal characteristics, and study the associated CMEs. We present a comprehensive catalog of DH type IV bursts observed by the Radio and Plasma Wave Investigation instruments on board the Wind and Solar TErrestrial RElations Observatory spacecraft covering the period of white-light CME observations by the Large Angle and Spectrometric Coronagraph on board the Solar and Heliospheric Observatory mission between 1996 November and 2023 May. The catalog has 139 bursts, of which 73% are associated with a fast (>900 km s⁻¹) and wide (>60°) CME, with a mean CME speed of 1301 km s⁻¹. All DH type IV bursts are white-light CME-associated, with 78% of the events associated with halo CMEs. The CME source latitudes are within ±45°. Seventy-seven events had multiple-vantage-point observations from different spacecraft, letting us explore the impact of the line of sight on the dynamic spectra. For 48 of the 77 events, there were good data from at least two spacecraft. We find that, unless occulted by nearby plasma structures, a type IV burst is best viewed when observed within a ±60° line of sight. Also, bursts with a duration above 120 minutes have source longitudes within ±60°. Our inferences confirm the inherent directivity in the type IV emission. Additionally, the catalog forms a Sun-as-a-star DH type IV burst database.